Microsoft has made available for download the June 2010 Release of the Visual Studio 2010 and .NET Framework 4 Training Kit.

The Visual Studio 2010 and .NET Framework 4 Training Kit includes presentations, hands-on labs, and demos. This content is designed to help you learn how to utilize the Visual Studio 2010 features and a variety of framework technologies including:
C# 4
Visual Basic 10
Parallel Extensions
Windows Communication Foundation
Windows Workflow
Windows Presentation Foundation
Windows 7
Entity Framework
ADO.NET Data Services
Managed Extensibility Framework
Visual Studio Team System

The size of the download file is 178.0 MB and you can download it here:

Channel 9 also has a bunch of video available, you can find all 41 videos here: