Microsoft has made available for download the June 2010 Release of the Visual Studio 2010 and .NET Framework 4 Training Kit.

The Visual Studio 2010 and .NET Framework 4 Training Kit includes presentations, hands-on labs, and demos. This content is designed to help you learn how to utilize the Visual Studio 2010 features and a variety of framework technologies including:
C# 4
Visual Basic 10
F#
Parallel Extensions
Windows Communication Foundation
Windows Workflow
Windows Presentation Foundation
ASP.NET 4
Windows 7
Entity Framework
ADO.NET Data Services
Managed Extensibility Framework
Visual Studio Team System

The size of the download file is 178.0 MB and you can download it here: http://www.microsoft.com/downloads/details.aspx?familyid=752CB725-969B-4732-A383-ED5740F02E93&displaylang=en

Channel 9 also has a bunch of video available, you can find all 41 videos here: http://channel9.msdn.com/shows/10-4/